Not sure about the rest of the world, but in the U.K. at least - the premium fuels contain cleaners, other additives and less ethanol so have a greater potential power per litre of fuel.
At Goodwood festival of speed once, BP had plumbed a different fuel to each half of a V8 and then run it for a few thousand miles. Looking through the spark plug holes with their camera - you could see so much carbon build up with regular fuels, but the premium fuel made the piston look brand new.
Higher ron should in theory also lead to a better range per tank full - which can be important on long adventures.
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